Methyl 5-bromo-2-[methyl(methylsulfonyl)amino]benzoate
نویسندگان
چکیده
The title compound, C(10)H(12)BrNO(4)S, is an inter-mediate in the synthesis of benzothia-zine. The planar methyl ester group (maximum deviation is 0.0065 Å) is oriented at a dihedral angle of 39.09 (13)° with respect to the aromatic ring. In the crystal structure, weak inter-molecular C-H⋯O inter-actions link the mol-ecules into centrosymmetric dimers, through R(2) (2)(10) ring motifs.
منابع مشابه
A nonmerohedral twin of methyl 2-[methyl(methylsulfonyl)amino]benzoate
The asymmetric unit of the title compound, C(10)H(13)NO(4)S, comprises two crystallographically independent mol-ecules. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds, which link mol-ecules along the b axis. The crystal is a nonmerohedral twin, the refined ratio of the twin components being 0.344 (2):0.656 (2).
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009